Large Titanite Shard - Crestfallen Merchant/ Slimes/ Giant Leech In Forest Hunter covenant drop for PvP kills when summoned (not 100%) Steel Knight in Painted World of Ariamis, just before Priscilla (100% droprate).
In NG, on average you can get a faster rate of twinkling titanite by farming the clams in crystal caves (~25 min for 99) than farming for the souls to buy them (~40 min painted world). Sometimes they will put their shield up first thing and block the fireball, but that is pretty rare. Behind an illusory wall near the Watchdogs of Farron covenant location. There should be another Darkwraith to kill with a running attack. It isn't necessary for one specific piece of equipment. Twinkling Titanite - Clams in Ash Lake (3), Clams in Crystal Caves (6) just prior to Seath the Scaleless battle, and Crystal Lizards after patch 1.05, Giant Blacksmith sells for 8000ea(infinite) Dragon Scale - Drakes in Valley of the Drakes, Drop from Hydras, found on corpses in various areas, also the undead dragons drop scales. Grass Crest Shield - very useful for letting you run more.
See also: Farming, Soul Farming, Humanity Farming. Items -20 estus flasks - you'll need these since you'll be constantly taking damage from the Symbol of Avarice. Using that bonfire, warp back to the Chaos Servant bonfire and do the same cycle again. NOTE: The path essentially consists of a 90 degree right turn followed by a 90 degree left turn, with straight sections in between. Obtained by trading with Snuggly the Crow in exchange for an egg vermifuge. With an Ascended Pyromancy Flame +5 they will die in 1 hit from these spells. Blue Titanite Chunk - Crystal Golems in Darkroot Basin, The Duke's Archive, and the Crystal Cave Black Knight(Halberd) in Kiln of the First Flame. +3 the weapon before even getting to Vordt. Follow the path through the wooden house-like structures until you exit into an open area. (you might want this if you're on NG+ or beyond). On your way down the last ramp to his fog gate there will be a path off to the right. Shrine handmaiden has an infinite amount of them for sale after you give her 'Dreamchaser's ashes' which are found.
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